By J. C. Bevington (auth.)
ISBN-10: 3540024948
ISBN-13: 9783540024941
ISBN-10: 3540370188
ISBN-13: 9783540370185
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Amer. chem. Soc. 79, 900 (1957). 14. , G. T. M. EABTHAM: J. Amer. chem. Soc. 82, 120 (1960). 15. MERRALL, G . T . , G. A. LATREMOUILLE and A. M. EASTHAM: unpublished. 16. , and M. TAMRES: J. Amer. chem. Soc. 73, 3704 (1951). 17. FARTHING, A. : J. chem. Soc. 1955, 3648. 18. RosE, J. ]3. : J. chem. Soc. 1956, 542. 19. RosE, J. : J. chem. Soc. 1956, 547. 20. EASTHAM, A. : J. Amer. chem. Soc. 78, 6040 (1956). 21. , W. C. E. HIGGII~SON, P. L~VESLEY and K. J. TAYLOR: J. chem. Soc. 1959, 1338. , W. C.
A) BF3 -+ II--(J--CH2CH2OH CH, H I -B'F3 (b) CH2CH2OH -B'F3 ] R - - O - - H . . O--R q- CH,CH, -+ R--O--H q- O--R \/ O CH,CH,O-- B~'~ / CH=--CH. \o / (c--i) R - - O - - H . . O \ > CH~CH20--- CH~CH~O-- +/ ROBF 3 9 HOCH2CH20 \ CH~CH20-- +/ CH,CHzO-- (c--ii) ROBF~-... HOCH~CH,O -J- --OCH2CH~OH \ CH2CH~O-- +/ --OCH~CH2OCH~CH2OH + ROBFf... HO CH2CH~O-- \ CH~CH20-- Of these, reaction (a) although rapid would soon disappear with chain growth because the epoxide would be displaced from the catalyst complex by filechain ether groups.
MEVR]~SCH: Chem. Ber. 85, 863 (1952); Chem. Ber. 86, 1322 (1953). 6. : D. R. P. 741, 478. 7. Dells, Microfilm F R 156148, Leverkusen (1941). 8. : Angew. Chem. 63, 231 (1951). 9. , T. TSUJUNO and Y. HACHIHAMA: Kogyo Kagaku Zasshi 61, 1347 (1958). 10. , a n d H. LOHMANN: Liebigs Ann. Chem. 505, 41 (1933). 11. COLCLOUGH, R. , G. GEE, W. C. E. HIGGINSON; J. B. JACKSON and M. LITT: J. Pol. Sci. 34, 171 (1959). 12. WORSFOLD, D. , a n d A. M. EASTHAM: J. Amer, chem. Soc. 79, 897 (1957). 13. WORSFOLD, D.
Fortschritte Der Hochpolymeren-Forschung by J. C. Bevington (auth.)
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