By Martel Zeldin, Kenneth J. Wynne, Harry R. Allcock
ISBN-10: 0841212074
ISBN-13: 9780841212077
ISBN-10: 0841214425
ISBN-13: 9780841214422
content material: An creation to inorganic and organometallic polymers / Kenneth J. Wynne --
Polysilane excessive polymers : an outline / Robert West and Jim Maxka --
Polycarbosilanes : an outline / Dietmar Seyferth --
Soluble polysilane derivatives : chemistry and spectroscopy / R.D. Miller, J.F. Rabolt, R. Sooriyakumaran, W. Fleming, G.N. Fickes, B.L. Farmer, and H. Kuzmany --
Poly(di-n-hexylsilane) in room-temperature answer : photophysics and photochemistry / J. Michl, J.W. Downing, T. Karatsu, K.A. Klingensmith, G.M. Wallraff, and R.D. Miller --
New artificial routes to polysilanes / okay. Matyjaszewski, Y.L. Chen, and H.K. Kim --
Polymerization of crew 14 hydrides by means of dehydrogenative coupling / John F. Harrod --
Polysilylene arrangements / D.J. Worsfold --
Characterization of copolydiorganosilanes with various compositions / Samuel P. Sawan, Yi-Guan Tsai, and Horng-Yih Huang --
man made routes to oligosilazanes and polysilazanes : polysilazane precursors to silicon nitride / Richard M. Laine, Yigal D. Blum, Doris Tse, and Robert Glaser --
Organosilicon polymers as precursors for silicon-containing ceramics : fresh advancements / Dietmar Seyferth, Gary H. Wiseman, Joanne M. Schwark, Yuan-Fu Yu, and Charles A. Poutasse --
NMR characterization of a polymethyldisilylazane / a precursor to Si-C-N-O ceramics / Jonathan Lipowitz, James A. Rabe, and Thomas M. Carr --
Silicon-nitrogen-containing jewelry and polymers / Z. Lasocki, B. Dejak, J. Kulpinski, E. Lesniak, S. Piechucki, and M. Witekowa --
fresh advances in organosiloxane copolymers / J.D. Summers, C.S. Elsbernd, P.M. Sormani, P.J.A. Brandt, C.A. Arnold, I. Yilgor, J.S. Riffle, S. Kilic, and J.E. McGrath --
Polysiloxanes functionalized with 3-(1-oxypyridinyl) teams : catalysts for transacylation reactions of carboxylic and phosphoric acid derivatives / Martel Zeldin, Wilmer okay. Fife, Cheng-xiang Tian, and Jian-min Xu --
Photochemical habit of organosilicon polymers bearing phenyldisilanyl devices / Mitsuo Ishikawa and Kazuo Nate --
Routes to molecular metals with generally variable counterions and band-filling : electrochemistry of a conductive natural polymer with an inorganic spine / Tobin J. Marks, John G. Gaudiello, Glen E. Kellogg, and Stephen M. Tetrick --
a brand new method of the synthesis of alkyl silicates and organosiloxanes / George B. Goodwin and Malcolm E. Kenney --
present prestige of polyphosphazene chemistry / Harry R. Allcock --
Phosphazene polymers : synthesis, constitution, and homes / Robert E. Singler, Michael S. Sennett, and Reginald A. Willingham --
Polyphosphazenes : functionality polymers for strong point purposes / H.R. Penton --
Poly(alkyl/arylphosphazenes) / Robert H. Neilson, R. Hani, G.M. Scheide, U.G. Wettermark, P. Wisian-Neilson, R.R. Ford, and A.K. Roy --
Hybrid inorganic-organic polymers derived from organofunctional phosphazenes / Christopher W. Allen --
Polybis(pyrrolyl)phosphazene / R.C. Haddon, S.V. Chichester, and T.N. Bowmer --
Skeletal stabilization because the foundation for synthesis of novel phosph(III)azane oligomers and polymers / Elizabeth G. Bent, Joseph M. Barendt, R. Curtis Haltiwanger, and Arlan D. Norman --
constitution of sol-gel-derived inorganic polymers : silicates and borates / C.J. Brinker, B.C. Bunker, D.R. Tallant, K.J. Ward, and R.J. Kirkpatrick --
Organically transformed silicates as inorganic-organic polymers / H.K. Schmidt --
Sol-gel training and homes of fibers and coating movies / S. Sakka, okay. Kamiya, and Y. Yoko --
New hybrid fabrics incorporating poly(tetramethylene oxide) into tetraethoxysilane-based sol-gel glasses : structure-property habit / Hao-Hsin Huang, Raymond H. Glaser, and Garth L. Wilkes --
Precursors to nonoxide macromolecules and ceramics / C.K. Narula, R.T. Paine, and R. Schaeffer --
Boron-nitrogen polymer precursors / S. Yvette Shaw, Donn A. DuBois, and Robert H. Neilson --
Boron nitride and its precursors / K.J.L. Paciorek, W. Krone-Schmidt, D.H. Harris, R.H. Kratzer, and Kenneth J. Wynne --
Electron delivery in and electrocatalysis with polymeric movies of metallotetraphenylporphyrins / B.A. White, S.A. Raybuck, A. Bettelheim, okay. Pressprich, and Royce W. Murray --
Electronically accomplishing movies of poly(trisbipyridine)-metal complexes / C. Michael Elliott, J.G. Redepenning, S.J. Schmittle, and E.M. draw back --
Copper chloride complexes with poly(2-vinylpyridine) / A.M. Lyons, E.M. Pearce, M.J. Vasile, A.M. Mujsce, and J.V. Waszczak --
Cationic and condensation polymerization of organometallic monomers / Kenneth E. Gonsalves and Marvin D. Rausch --
Soluble steel chelate polymers of coordination numbers 6, 7, and eight / Ronald D. Archer, Bing Wang, Valentino J. Tramontano, Annabel Y. Lee, and Ven O. Ochaya --
a brand new type of oligomeric organotin compounds / Robert R. Holmes, Roberta O. Day, V. Chandrasekhar, Charles G. Schmid, K.C. Kumara Swamy, and Joan M. Holmes --
NMR characterization of the compositional and configurational sequencing of tri-n-butyltin polymers / Jon M. Bellama and William F. Manders.
Read or Download Inorganic and Organometallic Polymers. Macromolecules Containing Silicon, Phosphorus, and Other Inorganic Elements PDF
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Additional info for Inorganic and Organometallic Polymers. Macromolecules Containing Silicon, Phosphorus, and Other Inorganic Elements
Sample text
MILLER ET AL. Soluble Polysilane Derivatives 45 Table I. 3 Table II. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1988. 46 INORGANIC AND ORGANOMETALLIC POLYMERS Spectral Properties and Polymer Morphology One of the most intriguing properties of catenated silane derivatives is their unusual electronic spectra (25). The observation that low molecular weight silicon catenates absorb strongly in the U V was first reported by Gilman (26,27) and has been extensively studied (25).
A) W. I. Patnode and R. W. S. 2,381,000 and 2,381,002 (1945); Chem. , (1945) 4888. (b) See also: Α. V. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1988. 42 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. INORGANIC AND ORGANOMETALLIC POLYMERS Topchiev, N. S. Nametkin and V. I. Setkin, Chem. , 4 (1952) 508; Dokl. Akad. Nauk SSSR, 82 (1952) 927. G. Fritz and A. Worsching, Z. anorg. allg. , 512 (1984) 103. S. Yajima, Am. Ceram.
Crosslinked network-type polymers are needed. Such structures can be generated in more than one way, but in the case of the polycarbosilanes they have, to date, been obtained mainly by thermolytic routes: thermal treatment (with or without other chemical additives) in the case of the Yajima polycarbosilanes and the thermolysis of t e t r a methylsilane in the case of the Bayer process-derived polycarbosilane. Although we have not discussed other types of polycarbosilanes, some may be mentioned to show what is available in terms of other specific examples of general formula 1.
Inorganic and Organometallic Polymers. Macromolecules Containing Silicon, Phosphorus, and Other Inorganic Elements by Martel Zeldin, Kenneth J. Wynne, Harry R. Allcock
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