By Donald T. Sawyer
ISBN-10: 0195057988
ISBN-13: 9780195057980
ISBN-10: 1423735544
ISBN-13: 9781423735540
This booklet areas oxygen at the middle level of chemistry in a way that parallels the focal point on carbon by way of nineteenth century chemists. One degree of the importance of oxygen chemistry is the higher variety of oxygen-containing molecules than of carbon-containing molecules. essentially the most vital compounds is water, containing the houses of being a special medium for organic chemistry and lifestyles, the resource of the entire dioxygen within the surroundings, and the moderator of the earth's weather. Sawyer first introduces the organic origins of dioxygen and function of dioxygen in cardio biology and oxidative metabolism, and in separate chapters discusses the oxidation-reduction thermodynamics of oxygen species, and the character of the bonding for oxygen in its compounds. extra chapters specialise in the reactivities of particular oxygen compounds. The publication may be of curiosity to chemists and biochemists, in addition to graduate scholars, lifestyles scientists, and scientific researchers.
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Extra resources for Oxygen Chemistry (International Series of Monographs on Chemistry)
Example text
T. /. Am. Chem. Soc. 1985,107,5712. 14. ; Sawyer, D. T. /. Org. Chem. 1985, 50,1784. 15. Sawyer, D. ; Roberts, J. ; Calderwood, T. ; McDowell, M. S. Phil. Trans. Roy. Soc. Land. 1985, 8311,483. 2 REDOX THERMODYNAMICS FOR OXYGEN SPECIES (03, O2, HOO-, O2'-, HOOH, HOO-, O, O-, AND HO); EFFECTS OF MEDIA AND pH One electron at a time Biological systems activate ground-state dioxygen (3O2) for controlled energy transduction and chemical syntheses via electron-transfer and hydrogen-atomtransfer reduction to O2~-, HOO-, and HOOH.
Electroanal. Chem. 1966,12,90. 30. Sawyer, D. ; Seo, E. T. Inorg. Chem. 1977,16,499. 31. Roberts, J. ; Morrison, M. ; Sawyer, D. T. /. Am. Chem. Soc. 1978,100,329. 32. McCord, J. ; Fridovich, I. /. Biol. Chem. 1968, 243,5753. 33. Nanni, E. ; Angelis, C. ; Sawyer, D. T. /. Am. Chem. Soc. 1981, 103, 4268. 34. Ortiz de Montellano, P. R. ). Cytochrome P-450: Structure, Mechanism, and Biochemistry. New York: Plenum, 1986. 35. Clarke, L. , Trans. Am. Soc. Artif. Intern. Organs 1956,2,41. 36. Sawyer, D.
Redox Thermodynamics for Oxygen Species 51 8. ; Sawyer, D. T. Anal. Chem. 1986,58,1057. 9. ; Sawyer, D. T. Inorg. Chem. 1986, 25,2089. 10. Sawyer, D. ; Roberts, J. ; Srivatsa, G. ). , 1984. 11. Roberts, J. L. ; Morrison, M. ; Sawyer, D. T. /. Am. Chem. Soc. 1978,100,329. 12. Roberts, J. ; Sawyer, D. T. Israel ]. Chem. 1983,23,430. 13. ; Chiericato, G. ; Nanni, E. ; Sawyer, D. T. /. Am. Chem. Soc. 1982, 204,1296. 14. Gibian, M. ; Sawyer, D. ; Morrison, M. M. /. Am. Chem. Soc. 1979,101,640. 15. Fridovich, I.
Oxygen Chemistry (International Series of Monographs on Chemistry) by Donald T. Sawyer
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