By Bryan L. Connelly
ISBN-10: 1616685131
ISBN-13: 9781616685133
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Extra resources for Chemical Crystallography (Chemistry Research and Applications)
Example text
295 Å). 4H2O148 comprises both modes. 149 (i) (ii) Figure 30. 5] (ii). (Reproduced by permission from reference 146). 44 A. Alvin Holder, C. Lesley Lewis-Alleyne, Don vanDerveer et al. Figure 31. 5])n. (Reproduced by permission from reference 149). 150 The tri-capped trigonal prismatic Ce(IV) chelate has also been observed in Ce(IV)-alkaline earth-dipic complexes 151-154. However, in all these cases some of the free oxygen atoms of the chelate coordinate to M(II) ions forming chains and networks.
616(5) Å, respectively. These V=O bonds are sufficiently short to imply double bonding with considerable character. 114 The similarity of the V=O bond distance in five-coordinate V(IV) and V(V) complexes show that this bond distance is dependent upon the geometry around vanadium center and not on oxidation state. 990(5) Å) coordinated trans to each other at axial positions. 989(2) Å)111 in which the carboxylate oxygen atoms are coordinated at axial positions. 089(6) Å. 84 The unit cell also contains one water molecule and a potassium ion.
149 (i) (ii) Figure 30. 5] (ii). (Reproduced by permission from reference 146). 44 A. Alvin Holder, C. Lesley Lewis-Alleyne, Don vanDerveer et al. Figure 31. 5])n. (Reproduced by permission from reference 149). 150 The tri-capped trigonal prismatic Ce(IV) chelate has also been observed in Ce(IV)-alkaline earth-dipic complexes 151-154. However, in all these cases some of the free oxygen atoms of the chelate coordinate to M(II) ions forming chains and networks. In the present cases there is no coordination link between the anions and cations.
Chemical Crystallography (Chemistry Research and Applications) by Bryan L. Connelly
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