Claudio De Rosa's Crystals and crystallinity in polymers : diffraction PDF

By Claudio De Rosa

ISBN-10: 0470175761

ISBN-13: 9780470175767

ISBN-10: 1118690443

ISBN-13: 9781118690444

ISBN-10: 1118690591

ISBN-13: 9781118690598

ISBN-10: 1118690796

ISBN-13: 9781118690796

ISBN-10: 1299848710

ISBN-13: 9781299848719

"Polymeric crystals are extra advanced in nature than different fabrics' crystal buildings because of major structural affliction current. actually, they really exist in a semicrystalline country the place the crystals are embedded in an amorphous part to create a hugely interconnected community. proposing an in-depth and present assessment of polymer crystals, Crystals and Crystallinity in Polymers presents researchers,

"This booklet offers a finished rationalization and evaluation of the advanced subject of polymer crystallography in a fashion that permits readers to guage polymer crystallization facts and ascertain which how you can make the most of for specific cases"-- Read more...

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Additional resources for Crystals and crystallinity in polymers : diffraction analysis of ordered and disordered crystals

Example text

If the rings are symmetrical with A = B, the polymers are designed meso-diisotactic and racemodiisotactic (21d). As discussed earlier, the general requirement for the crystallizability of polymers is the regularity in the 18 CONFIGURATION AND CONFORMATION OF MACROMOLECULES IN POLYMER CRYSTALS chemical constitution and in the configuration of long sequences of monomeric units (3,4,19). Copolymers of different monomers that are able to cocrystallize in the same lattice may be considered as possible exceptions to the need of the regularity in the chemical constitution.

The class of the helix is, therefore, A = 1. 5 Å, there are two conformational repeating units, that is, one monomeric unit (the repeating unit) (Fig. 22A). Similar twofold helical symmetry characterizes the nearly trans-planar conformation of nylon 6 (Fig. 22B) (55). The line repetition group is s(2/1)d for a perfect trans-planar conformation or s(2/1) for the conformation slightly distorted from the perfect fully extended trans-planar conformation (Fig. 22B) (55). The constitutional repeating unit for nylon 6 is –CO–(CH2)5–NH–, which corresponds to the conformational repeating unit, being the smallest structural unit that is repeated along the chain generating the whole chain through application of the twofold screw axis (Fig.

The relative configuration at two contiguous carbon atoms in the main chains bearing substituents A and B, respectively, with A ≠ B, is designed as erythro or threo (Fig. 10) (21d). This is in analogy with the terminology for carbohydrate systems in which the substituents are –OH (20a). Also in this case, the use of configurational signs (+) and (−) for the designation of the intrinsic chirality of bonds is very useful for the description of the relative configuration. Two configurational signs, for example, (+, −), can be assigned to the bond connecting the two stereoisomeric centers, assuming that substituents A and B have CIP priority compared to the hydrogen atom (Fig.

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Crystals and crystallinity in polymers : diffraction analysis of ordered and disordered crystals by Claudio De Rosa

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