By Professor Dr Victor E. Borisenko (auth.)
ISBN-10: 3642596495
ISBN-13: 9783642596490
ISBN-10: 3642640699
ISBN-13: 9783642640698
The ebook provides a complete presentation and research of homes and techniques of formation of semiconducting silicides
Fundamental digital, optical and shipping homes of the silicides amassed from fresh guides may also help the reader to select for his or her software in new generations of solid-state devices
A accomplished presentation of thermodynamic and kinetic information is given together with their technical application
Information on corresponding thin-film or bulk crystal formation thoughts is provided
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Extra info for Semiconducting Silicides
Sample text
76]. 76]. The phase diagram distinguishing the single phase and two-phase regions is presented in Fig. 24. It obeys all the characteristics of a true equilibrium diagram: change in crystalline parameter in the one region, 46 Victor E. Borisenko and Andrew B. Filonov coexistence of two phases in the right proportions in the two-phase region, and reversibility. The fonn of the diagram also implies that the hexagonalto-tetragonal transition of WSh is an allotropic transfonnation and that the hexagonal low temperature fonn of this disilicide is stable.
The conventional orthorhombic cell is rather large containing 48 atoms (16 formula units). 39]. Its origin will be discussed later (see electronic property section). Such a distortion could be easily traced by considering the deformation of the tetragonal nucleus of a cubic supercell made up by 8 fcc units with a being twice the fcc edge along x and b = c being the diagonals of the fcc square faces. As a result of the distortion a becomes shorter while b and c increase by slightly different values.
414·C 411D) U 'LW IX: 1000 => ~ « IX: w a.. ~ W ~ 800 727·C . - - - I 20 30 40 50 60 70 80 ATOMIC PER CENT SILICON 90 100 Si Fig. 18. 28. 26. 86]. 27. 1] Silicide Mn3Si Mn sSi 3 MnSi MnSi L ?? 889x 10-3T-4226078T-2 Temperature range (K) 588-1241 743 -1332 792 -1418 610-1402 38 E. 28. Borisenko and Andrew B. 52 Mn,Si 25910 25829 25680 25488 25265 25016 24746 24603 23204 21712 23381 23302 22912 22484 21976 MnsSh 30242 30205 30207 30248 30330 30352 30616 Mn ll Si 19 30735 32 122 32213 32424 32613 32 782 32873 34199 34356 36695 37510 37572 37841 38124 38422 38609 39394 39581 39628 40316 40712 34395 35939 35979 36015 36076 36176 36317 36507 Mn,Si 25607 25513 25450 25422 25428 25468 25541 25589 25589 25689 25689 25735 25997 26296 26634 MnsSh MnllSil9 31438 31853 32266 32 675 33073 33457 33823 33613 32810 32 012 31204 30383 29543 28683 34102 34102 34141 34323 34487 34636 34720 34720 34729 27977 27977 27782 26790 25773 24732 24096 24096 23643 23529 23529 22442 34731 Re-Si system.
Semiconducting Silicides by Professor Dr Victor E. Borisenko (auth.)
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