
By Giuseppe Allegra, A. Abe, Auriemma, S. Bracco, A. Comotti, P. Corradini, W.H.de Jeu, C. De Rosa, H. Furuya, T. Hiejima, Y. Kobayashi, L. Li, R. Simonutti, P. Sozzani, Z. Zhou
ISBN-10: 3540253440
ISBN-13: 9783540253440
This sequence offers serious stories of the current and destiny developments in polymer and biopolymer technology together with chemistry, actual chemistry, physics and fabrics technology. it's addressed to all scientists at universities and in who desire to maintain abreast of advances within the themes lined.
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Extra info for Interphases and Mesophases in Polymer Crystallization II (Advances in Polymer Science) (v. 2)
Sample text
25 A (Fig. 9A), are present [95–97]. 5 ˚ periodicity. Solid Mesophases in Semicrystalline Polymers: Structural Analysis 31 Fig. 9 Experimental X-ray diffraction intensity distribution of a PAN fiber (A) in the ξ, ζ reciprocal plane, (B) along the equator (for ζ = 0) and (C) along the meridian (for ξ = 0). (A) : Contour lines with constant I(ξ, ζ) values at regular intervals of two units (arbitrary scale). (Reprinted with permission from [97]. 5 A was taken as an indication that the pseudo-hexagonal crystalline form of PAN is formed by elongated portions of chains with a prevailing syndiotactic configuration in a nearly trans-planar conformation [39–48].
15B,B’ the chains are arranged as in the orthorhombic [194] and monoclinic [196] polymorphs of PE, respectively. In Fig. 15C,C’ the chains are arranged as in triclinic form of long chains paraffins [197]. These models were chosen as reference, “ideal” structures, where different kinds of disorder were introduced, in order to better understand their influence on the cal- 40 F. Auriemma et al. Fig. 16 (a) Experimental X-ray diffraction intensity distribution along the first layer line (l = 1) of a stretched sample of EP copolymer in the pseudo-hexagonal mesomorphic form (solid line).
In other terms, the mesomorphic form of EP copolymers may be described as aggregates of clusters chains arranged as in the orthorhombic- monoclinic- or even triclinic-like structures, to form larger bundles, in a mosaic-like structure, as schematically shown in Fig. 17; the interference between different clusters in the mesomorphic aggregate would produce only a background on non-equatorial layer lines [195]. According to the analysis of [195], the mesomorphic hexagonal form of EP copolymers is characterized by the following structural features: 1.
Interphases and Mesophases in Polymer Crystallization II (Advances in Polymer Science) (v. 2) by Giuseppe Allegra, A. Abe, Auriemma, S. Bracco, A. Comotti, P. Corradini, W.H.de Jeu, C. De Rosa, H. Furuya, T. Hiejima, Y. Kobayashi, L. Li, R. Simonutti, P. Sozzani, Z. Zhou
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